VDD and VSS vs GND and +5V

Can I route R2: pin 2 to IC3: pin 14 like this? (I’ve attached a zip file).

Also, I’ve tried to add some pins for an ICSP header. I see the datasheet for the PicKit3 shows that I should have a resistor between VPP and VDD. It says, A pull-up resistor (typically around 10 kohm)

is recommended to be connected from the VPP/MCLR line to VDD so that the line may

be strobed low to reset the device.

How does this look? Is there a specific header I should be using? From the data sheet, it almost looks like they have 6 pins in a straight row but on the net, I see people are using the 2x3 header. Thanks guys!