I’m sorry I can’t give you an answer but the two that you have now, Bluetooth and RFID, won’t have the distance of 100 m. RFID is likely to be no more than 1 to 2 m at the absolute best (usually less than 1 m) and Bluetooth will likely top out at 25 to 30 m.
This is outside of my knowledge area but some thoughts. Will these be line of sight where you could use IR (don’t forget ambient light will reduce range)? 802.11?