vcc vdd vss terminology

I have a circuit that uses a number of rails. Namely 5v, 12v, 3.3v

What is a good way to handle the terminology in Eagle?

From the sparkfun eagle library I have been adding ground, and vcc “components” into my diagram but they don’t differentiate the different voltages… What is standard practice in this area?

The supply and sparkfun libraries contain “3.3V” etc symbols, which you should use (plus its more specific). Note that the supply libraries prefix with +, whereas Sparkfun does not (and that does matter when you use both ;)).